In
high pressure processing, the hydrostatic pressure was generated by increasing
the free energy with physical compression during pressure treatment in closed
system by mechanical volume reduction. Besides that, the HPP accompanied by a
moderate increase in temperature, called as the adiabatic heating, which
depends on the composition of the food product being processed. There are 3
principles that are apply in HPP method.
Le
Chatelier’s principle:
Any
phenomenon (phase transition, change in molecular Configuration, chemical
reaction) accompanied by a decrease in volume is enhanced by pressure.
Accordingly, pressure shifts the system to that of lowest volume. According to
this principle whenever a stress is applied to a system in equilibrium, the
system will react so as to counteract the applied stress, reactions that result
in reduced volume will be promoted under high pressure, such reactions may
result in inactivation of microorganisms or enzymes.
Isostatic
principle:
Food products are compressed by uniform
pressure from every direction and then returned to their original shape when
the pressure is released. The products are compressed independently of the
product size and geometry because transmission of pressure to the core is not
mass/time dependent thus the process is minimized If a food product contains
sufficient moisture, pressure will not damage the product at the macroscopic
levels as long as the pressure is applied uniformly in all directions.When food
products are compressed by uniform pressure from every direction and then
returned to their original shape when the pressure is released.
Microscopy
ordering principle:
at constant temperature, an increase in
pressure increases the degrees of ordering of molecules of a given substance. Therefore,
pressure and temperature exert antagonistic forces on molecular structure and
chemical reactions.
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